Res. Agr. Eng., 2023, 69(3):124-131 | DOI: 10.17221/70/2022-RAE

Enhanced biodiesel production from waste cooking oils catalyzed by sodium hydroxide supported on heterogeneous co-catalyst of bentonite clayOriginal Paper

Darwin Darwin, Rini Ayu Marisa Harahap, Atmadian Pratama, Muhammad Thifa, Muhammad Alwi A Fayed
Department of Agricultural Engineering, Faculty of Agriculture, Universitas Syiah Kuala, Banda Aceh, Indonesia

Various proportions of bentonite clay performing as co-catalysts were evaluated for the production of biodiesel from waste cooking oil (WCO). The results showed that the use of bentonite as a heterogeneous co-catalyst could significantly increase the biodiesel yield by approximately 50% of the control. The heterogeneous co-catalyst of bentonite clay improved the properties of the produced biodiesel including acid number, free fatty acids (FFA), relative density, kinematic viscosity and flash point fulfilling with the standard ASTM limits and the European Biodiesel Standard (EN 14214). The use of bentonite clay in the transesterification of WCO could also enhance the conductivity of the produced biodiesel from 11 to 100 µS·m–1.

Keywords: biofuel; heterogeneous catalyst; biodiesel, used frying oil

Accepted: February 9, 2023; Prepublished online: August 3, 2023; Published: September 3, 2023  Show citation

ACS AIP APA ASA Harvard Chicago Chicago Notes IEEE ISO690 MLA NLM Turabian Vancouver
Darwin D, Harahap RAM, Pratama A, Thifa M, Alwi Fayed MA. Enhanced biodiesel production from waste cooking oils catalyzed by sodium hydroxide supported on heterogeneous co-catalyst of bentonite clay. Res. Agr. Eng. 2023;69(3):124-131. doi: 10.17221/70/2022-RAE.
Download citation

References

  1. Adamis Z., Williams R.B., Fodor J. (2005): Bentonite, kaolin, and selected clay minerals (Environmental Health Criteria 231). World Health Organization.
  2. Alhassan Y., Kumar N., Bugaje I.M., Pali H.S., Kathkar P. (2014): Co-solvents transesterification of cotton seed oil into biodiesel: effects of reaction conditions on quality of fatty acids methyl esters. Energy Conversion and Management, 84: 640-648. Go to original source...
  3. Alade A.F., Latifat A.T., Ishola M.S., Alhassan M.I., Bamidele S.H., Olawale A.E., Samuel O.S. (2021): Heterogeneous catalysis using bentonite-supported fe-co-ni trimetallic nanoparticles. Journal of Engineering Studies and Research, 27: 7-19. Go to original source...
  4. Amalia D., Aziz M., Cahyono S.S. (2010): Alternative method of the activation process for bentonite mineral. Indonesian Mining Journal, 13: 101-107.
  5. Bokhari A., Chuah L.F., Yusup S., Klemeš J.J., Akbar M.M., Kamil R.N.M. (2016): Cleaner production of rubber seed oil methyl ester using a hydrodynamic cavitation: Optimisation and parametric study. Journal of Cleaner Production, 136: 31-41. Go to original source...
  6. Borges M.E., Díaz L. (2012): Recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: A review. Renewable and Sustainable Energy Reviews, 16: 2839-2849. Go to original source...
  7. Buasri A., Ksapabutr B., Panapoy M., Chaiyut N. (2012): Biodiesel production from waste cooking palm oil using calcium oxide supported on activated carbon as catalyst in a fixed bed reactor. Korean Journal of Chemical Engineering, 29: 1708-1712. Go to original source...
  8. Burton R. (2008): An overview of ASTM D6751: Biodiesel Standards and Testing Methods. Sanford: Alternative Fuels Consortium, Sanford, Central Carolina Community College.
  9. Chidi O., Peter O.I. (2016): The use of eco-friendly catalyst in the production of ester. Makara Journal of Science 20: 199-205. Go to original source...
  10. Darwin, Charles W., Cord-Ruwisch R. (2019a): Anaerobic acidification of sugar-containing wastewater for biotechnological production of organic acids and ethanol. Environmental Technology, 40: 3276-3286. Go to original source... Go to PubMed...
  11. Darwin, Purwanto S., Rinaldi R. (2019b): Removal of organic pollutants from tofu-processing wastewater through anaerobic treatment process with short hydraulic retention time. Environmental Research, Engineering and Management, 75: 34-42. Go to original source...
  12. Darwin, Pratama A., Mardhotillah (2020): A synthesis of biodiesel on the ground of cooking oil using lignocellulosic residues as a heterogeneous catalyst and alcohol solvents. Journal of Chemical Technology & Metallurgy, 55: 778-784.
  13. Darwin, Pratama A., Mardhotillah (2021a): Biodiesel production from waste frying oils by potassium methoxide supported on activated carbon catalysts from lignocellulosic biomass. Acta Technologica Agriculturae, 24: 153-158. Go to original source...
  14. Darwin, Pratama A., Mardhotillah (2021b): Organic waste conversion via continuous anaerobic co-digestion of oil palm empty fruit bunches and cow manure: evaluation of feeding regime on methane production. Acta Technologica Agriculturae, 24: 8-13. Go to original source...
  15. El-Gharbawy A.S., Sadik W.A., Sadek O.M., Kasaby M.A. (2021): A review on biodiesel feedstocks and production technologies. Journal of the Chilean Chemical Society, 66: 5098-5109. Go to original source...
  16. Esmaeili H. (2022): A critical review on the economic aspects and life cycle assessment of biodiesel production using heterogeneous nanocatalysts. Fuel Processing Technology, 230: 107224. Go to original source...
  17. Guo S., Yang Z., Gao Y. (2016): Effect of adding biodiesel to diesel on the physical and chemical properties and engine performance of fuel blends. Journal of Biobased Materials and Bioenergy, 10: 34-43. Go to original source...
  18. Hájek M., Skopal F. (2010): Treatment of glycerol phase formed by biodiesel production. Bioresource Technology, 101: 3242-3245. Go to original source... Go to PubMed...
  19. Jacobson K., Gopinath R., Meher L.C., Dalai A.K. (2008): Solid acid catalyzed biodiesel production from waste cooking oil. Applied Catalysis B: Environmental, 85: 86-91. Go to original source...
  20. Jamil F., Kumar P.S.M., Al-Haj L., Myint M.T.Z., Ala'a H.A.M. (2020): Heterogeneous carbon-based catalyst modified by alkaline earth metal oxides for biodiesel production: Parametric and kinetic study. Energy Conversion and Management: X, 10: 100047. Go to original source...
  21. Karmakar R., Kundu K., Rajor A. (2018): Fuel properties and emission characteristics of biodiesel produced from unused algae grown in India. Petroleum Science, 15: 385-395. Go to original source...
  22. Mahmudul H.M., Hagos F.Y., Mamat R., Adam A.A., Ishak W.F.W., Alenezi R. (2017): Production, characterization and performance of biodiesel as an alternative fuel in diesel engines - A review. Renewable and Sustainable Energy Reviews, 72: 497-509. Go to original source...
  23. Okechukwu O.D., Joseph E., Nonso U.C., Kenechi N.O. (2022): Improving heterogeneous catalysis for biodiesel production process. Cleaner Chemical Engineering, 3: 100038. Go to original source...
  24. Oliveira A.D.N., Barbosa de Lima M.A., de Oliveira Pires L.H., Rosas da Silva M., Souza da Luz P. T., Angélica, R.S., da Rocha Filho G.N., da Costa C.E.F., Luque R., do Nascimento S.L.A. (2019): Bentonites modified with phosphomolybdic heteropolyacid (HPMo) for biowaste to biofuel production. Materials, 12: 1431. Go to original source... Go to PubMed...
  25. Rice E.W., Baird R.B., Eaton A.D. (2017): Standard Methods for the Examination of Water and Wastewater. 23rd Ed. Washington, American Public Health Association.
  26. Ramos M., Dias A.P.S., Puna J.F., Gomes J., Bordado J.C. (2019): Biodiesel production processes and sustainable raw materials. Energies, 12: 4408. Go to original source...
  27. Sakthivel R., Ramesh K., Purnachandran R., Shameer P.M. (2018): A review on the properties, performance and emission aspects of the third generation biodiesels. Renewable and Sustainable Energy Reviews, 82: 2970-2992. Go to original source...
  28. Singh R.K, Padhi S.K. (2009): Characterization of jatropha oil for the preparation of biodiesel. Natural Product Radiance, 8: 127-132.
  29. Ulakpa W.C., Ulakpa R.O., Eyankware E.O., Egwunyenga, M.C. (2022): Statistical optimization of biodiesel synthesis from waste cooking oil using NaOH/bentonite impregnated catalyst. Cleaner Waste Systems, 3: 100049. Go to original source...
  30. Yuan P., Lin B.Y. (2008): Measurement of viscosity in a vertical falling ball viscometer. American Laboratory, 40: 32-35.
  31. Wu L., Wei T.Y., Tong Z.F., Zou Y., Lin Z.J., Sun J.H. (2016): Bentonite-enhanced biodiesel production by NaOH-catalyzed transesterification of soybean oil with methanol. Fuel Processing Technology, 144: 334-340. Go to original source...

This is an open access article distributed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International (CC BY NC 4.0), which permits non-comercial use, distribution, and reproduction in any medium, provided the original publication is properly cited. No use, distribution or reproduction is permitted which does not comply with these terms.